--> Assessment of Temporal Source Rock Variability: An Example From the Lower Jurassic Posidonia Shale

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Assessment of Temporal Source Rock Variability: An Example From the Lower Jurassic Posidonia Shale

Abstract

The assessment of the natural temporal variability of source rock units is critical for the understanding of petroleum systems as changes in mineral matrix, organic matter (OM) concentration and composition can significantly affect expulsion efficiency, primary and secondary migration processes, hydrocarbon quality as well as oil source rock correlation. Already small-scaled fluctuations within sediment successions can critically influence migration efficiency. High-resolution investigation of a well-preserved Lower Jurassic drill core (Toarcian Posidonia Shale) revealed seven discrete and systematic intervals of deviating source rock quality. These were composed of homogenized, non-laminated marls of light grey color, opposed to laminated dark grey background sedimentation. Both lithotypes differentiate not only in mineral composition, but particularly in OM content and quality. An average TOC content of app. 3.9 wt.% reached by the grey marl, is faced by an average TOC content of app. 7.8 wt.% measured for the laminated dark grey marls. Average hydrogen index for grey non-laminated marls was app. 550 mg HC/g TOC, whereas much higher source rock quality with 780 mg HC/g TOC was attained in the dark laminated marls. The marls lower OM concentration and inferior OM quality generates important domains for preferential migration of products, originated from the dark grey layers, or hydrocarbon cluster in case of limited migration into adjacent reservoirs. To assess the potential for preferential intake of hydrocarbons by the coarser-grained light marls and their qualification as migration avenues, artificial maturation experiments were performed with both lithotypes. Hydrocarbon generation was simulated by hydrous pyrolysis in two successive temperature steps 330 °C and 360 °C), covering an early maturity stage, as well as the end of the oil window. Both lithologies show striking differences, not only for the extract yield, but also for the timing of generation. OM quality differences were reflected by variable n-alkane distributions and molecular maturity parameters. High-resolution continuous data produced by non-destructives techniques allows to draw conclusions on i) source rock potential, ii) expulsion and migration processes and iii) on prediction of petroleum accumulation within the sediment succession. High-resolution investigation in combination with artificial maturation experiments represent an easy-to-use tool in petroleum system analysis.