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Table 3. Kinetic Parameters for Standard Type II and Type II-S Kerogens*
  Standard Type II** Type II-S† Monterey Initial Potential (mg/g OC) Type II-S† Kirkuk Initial Potential (mg/g OC)
Oil potential from kerogen (mg/g TOC) 350 350   350
Gas potential from kerogen (mg/g TOC) 65  
Oil to gas cracking efficiency (%) 50  
A factor, hydrocarbon generation (1/s) 3.012 x 1013 1.5 x 1014   1.5 x 1014
A factor, oil cracking (1/s) 1.015 x 1012  
Activation energy foroil cracking (kcal/mol) 54  
Activation energy for hydrocarbon generation (kcal/mol); fraction††          
40 0.003 2 0.026 12.8
42   0.0183 9
44 0.0137 9 0.0098 4.8
46 0.0222 14.5 0.0154 7.6
48 0.3106 203.3 0.0601 29.6
49 0.05
50 0.2 0.4349 284.7 0.7903 389
51 0.5
52 0.2 0.1448 94.8 0.061 30
53 0.05
54 0.052 34 0.013 6.4
56 0.0104 6.8 0.0061 3
58 0.0038 2.5
60 0.0046 3

*OC = organic carbon, TOC = total organic carbon.
**Lawrence Livermore National Laboratory kinetics (Burnham and Sweeney, 1989).
†Type II-S kinetics (Tissot et al., 1987).
††Fraction of the kerogen having bonds with a particular activation energy.

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Last Updated on 6/17/98
By Jennifer Bennett