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AAPG ACE 2018

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A Multiproxy Geochemical Approach to Unraveling Hydrocarbon Charge History of the Triassic Shublik Formation of Arctic Alaska

Abstract

The Triassic marine carbonate Shublik Formation is a key source Previous HitrockNext Hit for hydrocarbons in the North Slope of Alaska. Although lithological heterogeneity and thickness variability of the Shublik Formation is widely recognized, most of the literature refers to it as one source Previous HitrockNext Hit unit. In addition, previous studies of oil types in the vicinity of the Northstar Field suggested presence of “shaly” organofacies of the Shublik Formation, however there remains a gap between biomarker analysis of predicted “calcareous” and “shaly” oil types and source Previous HitrockNext Hit geochemistry.

This study of the Shublik Formation investigates how lithologic heterogeneity relates to the distribution of source Previous HitrockNext Hit properties through detailed core-based analysis of the Tenneco Phoenix-1 well (OCS-Y-0338), drilled in offshore Arctic Alaska in 1986. Samples from different lithologies were collected for total organic carbon, Previous HitRockNext Hit-Eval pyrolysis, carbonate content, elemental analysis, and analysis of biomarkers and diamondoids. The core was also scanned at 1-ft intervals, using a hand-held x-ray fluorescence (XRF) device. The Shublik Formation in the Phoenix-1 well was subdivided into two nonsource and four source-Previous HitrockNext Hit intervals based on TOC and Previous HitRockNext Hit-Eval pyrolysis results, and distinctive geochemical, lithologic and XRF chemostratigraphic features. In four identified source Previous HitrockNext Hit intervals, biomarker analysis indicates the presence of two organic facies deposited under anoxic clay-poor and suboxic clay-rich environments. Both organofacies are characterized by oil-prone type I kerogens and are immature to marginally mature. Additionally, analysis of biomarkers and diamondoids combined with Previous HitRockNext Hit-Eval pyrolysis results yields evidence of mature migrated hydrocarbons that may have affected previous interpretations of organic matter type and maturity of this core.

Furthermore, current work fills the gap between biomarker analysis of two genetically-distinct organofacies and predicted oil families. Chemometric evaluation of multivariate biomarker data reveals mixtures with variable degrees of mixing between end members. Analysis of diamondoids confirms mixed oil types and establishes diamondoid signatures of source Previous HitrockNext Hit end-members. This allows for correlation of biomarker-poor, overmature Shublik source Previous HitrockTop samples to oils, and extends these interpretations over large areas of the North Slope.