--> Effects of Porosity Models on Thermal History Estimated by Geohistory Models
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Effects of Previous HitPorosityNext Hit Models on Thermal History Estimated by Geohistory Models

Abstract

Paleotemperature modeled by geohistory simulation is controlled by ancient surface temperature, heatflow (HF), and thermal conductivity (TC). The problems associated with estimating grain TC are well recognized by the literature, but the influence of Previous HitporosityNext Hit uncertainty on TC and paleotemperature is not so well recognized. In commercial geohistory software, Previous HitporosityNext Hit is calculated as an exponential function of Previous HitmaximumNext Hit burial Previous HitdepthNext Hit or effective stress, but Previous HitporosityNext Hit loss is actually a function of effective stress and time (by cementation and mineralogical conversion). Previous HitPorosityNext Hit models calibrated to current Previous HitporosityNext Hit may underestimate ancient Previous HitporosityNext Hit. Lower Previous HitporosityNext Hit causes higher TC, so paleo temperatures estimated from a modeled HF will be underestimated. This effect can be substantial for mudrocks. One solution is to modify the Previous HitporosityNext Hit models to better match observed physical processes. Transient sandstone and limestone Previous HitporosityNext Hit loss can be modeled using published algorithms. For mudrocks, the most robust approach is to divide Previous HitporosityNext Hit into free water and bound water. Model the free water loss using the standard compaction equilibrium approach. Model the transient bound-water loss by clay reactions. Bound water content is related to the cation exchange capacity (CEC) of the rock. The CEC and bound water will decrease significantly as smectite converts to illite. As CEC decreases, total Previous HitporosityNext Hit decreases. Smectite-illite conversion kinetics are available in the literature. Unfortunately, transient Previous HitporosityNext Hit models cannot be implemented into the current commercial geohistory programs, but they can be incorporated into research software. Transient models reduce Previous HitporosityNext Hit with time, so models calibrated to modern Previous HitporosityNext Hit correctly estimate current temperatures and modern HF but underestimate paleotemperatures where HF is constant. If modern Previous HitporosityNext Hit is estimated from literature mechanical compaction models and strata are old, modeled modern TC and modern HF may be underestimated. As an empirical short-term solution for commercial software users, Previous HitporosityNext Hit models can be calibrated to modern Previous HitporosityNext Hit-Previous HitdepthNext Hit, and the effects of lower paleo TC can be compensated by increasing paleo HF and surface temperature. We do this anyway when HF history is modified to match thermal indicators. Thus, geodynamic interpretations of higher paleo HF derived by fitting HF history to thermal indicators using current Previous HitporosityNext Hit-Previous HitdepthTop models may be invalid.