WU MAOBING, Lanzhou Institute of Geology, Chinese Academy of Sciences, Lanzhou, P.R. China
ABSTRACT: Volcanic Rocks and Their Effects on Hydrocarbon Generation
Many oil reservoirs are often related with volcanic activities in the
rift basins of eastern China. In order to evaluate how great potential effects of volcanic
products on hydrocarbon generation of immature
source
rocks, I collected some lacustrine
shales and volcanic rocks which interbed with shales and sandstones from Jurassic Xiaoling
Formation in Kuandian Basin,
east
of Liaoning Province, and measured separately the
volatile contents (especially H2, CH4) of
source
rock
, volcanic
rock
, and a mixture of the
source
rock
and volcanic
rock
with a MAT-271 mass spectrometer
by step-heating process. Experimental results reveal that volcanic rocks could provide H2
and CH4 to
source
rocks for hydrocarbon generation, especially fresh basic
volcanic rocks (H2 15 ~ 40µl STP/g), neutral and altered basic volcanic rocks
have H2 less than 18µl STP/g. The volatile contents of H2 and CH4
in the Mixture of
source
rock
and volcanic
rock
both increase sharply with the increase of
pyrolysis temperature from 200 degrees C to 400 degrees C , but have an inverse relation
when the heating temperature is over 400 degrees Cwith a decrease of H2 content
and an increase of CH4 36 times higher than the CH4 products of
source
rock
and volcanic
rock
separately. So it can be deduced that volcanic activity not
only provides heat and H2 but also may induce some catalysis reactions by
volcanic material to promote hydrocarbon generation.
AAPG Search and Discovery Article #90909©2000 AAPG Foundation Grants-in-Aid