Lithogenesis of Halite-Carnallite Veins in the Gorleben
Salt
Dome
FISCHBECK, REINHARD R., OTTO BORNEMANN, and GERHARD MINGERZAHN
Halite-carnallite veins were observed at a depth of 355 m when an exploration
mine shaft was sunk in the Gorleben salt
dome
. Gorleben is located in NW Germany
near the Elbe river. The
salt
dome
is being considered as a site for permanent
storage of radioactive waste materials. The long-term integrity of a
salt
dome
can best be assessed by the study of mineral reactions and mineral substance
transport which occurred primarily during the formation of the
dome
and in the
geological past. Harmful substances can be transported to the biosphere from a
permanent repository in a
salt
dome
by aqueous solutions only. Therefore,
understanding how the halite-carnallite veins were formed in the geological past
is important for the evaluation of the future integrity of the
salt
dome
.
We propose a model for the formation of the halite-carnallite veins which is
based on petrographic examinations and the fact that the bromine content of the
chloride salt
minerals of the veins can be used as an indicator of their genetic
origin and the rubidium content can be used as an indicator for the
potassium-bearing
salt
minerals. Halite was formed when solutions rich in
MgCl[2] from within the
salt
dome
mixed with NaCl solutions from the fringe of
the
salt
dome
or from outside. The MgCl[2] solutions are of metamorphic origin
or remnant solutions from the Zechstein sea. The fractures were not completely
filled by the crystallization of hypidiomorphic halite. Later, the 1 to 2 cm
thick sulfate layers which permeate the wall rock acted as pathways for MgCl[2]
solutions rising from the hot lower regions of the
salt
dome
. Carnallite then
crystallized in the remaining voids due to the drop in temperature.