--> ABSTRACT: New Kinetic Method for Modeling Oil Generation, by Longjiang Wang and Colin Barker; #91022 (1989)
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New Kinetic Method for Modeling Oil Generation

Longjiang Wang, Colin Barker

An extended kinetic method for modeling oil generation has been developed. The method can be used to calculate the amount of oil generated by a Previous HitsourceNext Hit Previous HitrockNext Hit, the amount migrated out of that Previous HitsourceNext Hit Previous HitrockNext Hit, and the expulsion efficiency. It can also be used to establish the time of oil generation and migration and to evaluate the evolving thermal maturity of the organic matter in the Previous HitsourceNext Hit Previous HitrockNext Hit.

The method incorporates a mass balance of all of the organic materials in a Previous HitsourceNext Hit Previous HitrockNext Hit. It treats the kerogen in the Previous HitsourceNext Hit Previous HitrockNext Hit as two parts, one convertible and the other nonconvertible. On heating, the convertible part of kerogen transforms only to hydrocarbons, and the nonconvertible part either remains unchanged (forming a carbon residue) or forms nonhydrocarbons (water, carbon dioxide, etc). Unlike other proposed models, the new method does not require a knowledge of the initial amount of organic matter in a Previous HitsourceNext Hit Previous HitrockNext Hit in order to model oil generation. The input data are derived solely from a study of the Previous HitrockNext Hit as it is today. Two assumptions are made in developing the method: (1) oil generation can be described by a group of first-order parallel reactions and (2) the total amo nt of oil that can be generated from a Previous HitsourceNext Hit Previous HitrockNext Hit is a constant. The input data required for the model include the amount of bitumen derived from dry pyrolysis (S1), the amount of kerogen pyrolysate (S2) also derived from dry pyrolysis, the kinetic parameters (E and A) of the kerogen, and the geothermal history of the Previous HitsourceNext Hit Previous HitrockTop.

AAPG Search and Discovery Article #91022©1989 AAPG Annual Convention, April 23-26, 1989, San Antonio, Texas.