Density
Distributions and CO2 Sorption in a Confined Coal Sample for Carbon
Sequestration
Jikich, Sinisha
A.1, Robert McLendon2, Duane H. Smith2 (1)
National Energy Technology Laboratory/Parsons, Morgantown, WV (2) National Energy
Technology Laboratory/U.S. DOE, Morgantown,
A confined core of a Pittsburgh #8 coal
obtained from a mine near Waynesburg, Pennsylvania, has been investigated
using computerized tomography. The 3-D density distribution of the coal was
calculated for the stressed and confined core with, and without CO2 sorption.
We used a dual energy technique to quantify volumetric variations in bulk
density and effective atomic number. CO2 sorption of coal was then investigated
at predetermined injection pressures. The density changes in the coal matrix
were calculated and correlated with the CO2 adsorbed for a multitude of regions
of interest (ROI) chosen in slices perpendicular to the bedding plane. The
results show that even in small core samples, coal heterogeneity is high. Large
variation of density was observed in small regions of interest compared to the
average density of slices. Also, the coal density distribution was changed
significantly due to the CO2 uptake. This technique seems very useful in
calculating density distribution for stressed and confined coal samples and the
change in volumetric density distribution due to CO2 adsorption. Furthermore
the kinetics of heterogeneous adsorption and swelling in coal can be
determined.