--> Abstract: Organofacies and Kerogen Transformation Kinetics: Implications for Hydrocarbon Generation in the Bucomazi Formation, Lower Congo Coastal Basin, by R. Burwood, G. Fortems, B. Mycke, J. Paulet, and S. M. De Witte; #90990 (1993).

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BURWOOD, R., G. FORTEMS, B. MYCKE, J. PAULET, and S. M. DE WITTE, Petrofina S.A., Brussels, Belgium

ABSTRACT: Organofacies and Kerogen Transformation Kinetics: Implications for Hydrocarbon Generation in the Bucomazi Formation, Lower Congo Coastal Basin

Deposited under lacustrine conditions during the rift-phase opening of the southern Atlantic, the lower Congo Bucomazi Formation is a highly productive source rock sequence. Reaching considerable thickness (1.8 km), a heterogeneous organofacies reflects both rapid accumulation and changing conditions during Early Cretaceous Barremian sedimentation.

As a component of organofacies, low resolution studies showed kerogen kinetic parameters (Ea/A) varied widely according to the gross paleoenvironmental conditions prevailing during deposition. As a general trend, refractory (type I, higher Ea) kerogens of the "basin fill" Organic Rich Zone (ORZ) give way to more labile (type II, lower Ea) assemblages in the up-section "sheet drape" sediments. At higher resolution, a considerable fine structure in Ea fluctuation, presumably reflecting micropaleoenvironment control, becomes evident.

Using Ea values assembled for the Bucomazi type section, subsidence modeling for a Ponta Vermelha depocenter section showed a wide disparity in behavior. Being more representative of the sheet-drape episode, type II assemblages matured earlier, at lesser overburdens, and provided the initial hydrocarbon charge. For the ORZ assemblages, the dominant type I component was of retarded maturation, only becoming productive at commensurately greater overburdens.

Cumulatively, these events merge to provide an extended period of hydrocarbon generation with implications for production of aggregate oils of varied emplacement histories. Significantly, the net effect of the observed Ea contrast results in the less prolific (but more labile) uppermost Bucomazi assuming a more important charging role than the ORZ of superior source richness. The latter can only realize its full potential under the greatest overburdens attainable in the most subsident depocenters.

AAPG Search and Discovery Article #90990©1993 AAPG International Conference and Exhibition, The Hague, Netherlands, October 17-20, 1993.